There are many uses to which the Equation of Time has been used.
ASTRONOMICAL
Since Ptolemy's Almagest, written around 150 CE, was published, astronomers have been tabulating and using the Equation of Time - primarily for predicting lunar movement.
NAVIGATIONAL
With introduction of accurate clocks (e.g. those introduced by John Harrison in 1759) and the publication of accurate tables of the Equation of Time (e.g. those by Christian Huygens in 1673 - see below - and subsequently the Nautical Almanac 1767 and Connaissance des Temps in 1679, longitude could at last be simply calculated with sufficient precision for navigators.
It may be proper first to premise, that for all Calculations are made according to apparent Time by the Meridian of the Royal Observatory at Greenwich.
What are shown concerning the Equation of Time chiefly respects the Astronomer, the Mariner having little to do with it in computing his Longitude from the Moon's Distances from the Sun and Stars with the Help of the Ephemeris, all the Calculations therefore being adapted to apparent Time, the same which he will obtain by the Altitudes of the Sun or Stars in the Manner hereafter prescribed,
But if the Watches made upon Mr John Harrison's or other equivalent Principles should be brought into Use at Sea, the apparent Time deduced from the Altitude of the Sun must be corrected by the Equation of Time, and the mean Time found compared with that shown by the Watch, the Difference will be the Longitude in Time from the Meridian by which the Watch was set; as near as the Going of the Watch* can be depended upon. (* Going of the Watch = Accuracy)
At a port of known longitude and where astronomers could measure time from the stars, the mariner would observe the firing of the noon cannon or the falling of the noon ball. At this moment, the chronometer was set to local mean time at that location. When at sea, the navigator would used his sextant to measure when the sun reached its zenith. This was 12:00 hrs Solar Noon. 12:00 + EoT was thus Local Mean Noon. The difference between Local Mean Noon at the ship and Local Mean Time at the port as shown on the chronometer was the longitudinal difference between the two places in hours. This was multiplied by 15 to give the longitudinal difference in degrees.
SUN COMPASSES
In the Second World War, Sun Compasses were developed to replace magnetic compasses in iron structured tanks & jeeps. They were used in the desert or jungles where maps were of no use. These were, in effect, stereoscopic sundials working backwards. One needed to know the time from radio broadcasts, then one could deduce the direction of North, To use, one had to have some idea of ones latitude. Two of the Sun Compasses had the Equation of Time built into their design.